Visible spectrophotometric analysis of cobalt and

The concentration of Cobalt in the organic phase was determined with 2-nitrosonaphtol [19] by photometric measurements after back extraction, while in the aqueous phase it was determined by the difference.

View at Scopus L. We are now reporting a simple, sensitive, and selective second-order derivative spectrophotometric method for the simultaneous determination of Fe II and Co II using HNAHBH without the need to solve the simultaneous equations.

Hence Fe II was determined by measuring the derivative amplitudes at nm for 1st order, at nm and nm for 2nd order, and at nm and nm for 3rd order spectra.

Complex formation and liquid-liquid extraction were studied in a system containing cobalt II4- 2-pyridylazo resorcinol PAR1,4-diphenyl phenylamino -1H-1,2,4- triazole Nitron, Ntwater, and chloroform.

Other approaches aimed at solving this problem have been used; including pH-induced differential spectrophotometry [ 6 ], least squares [ 7 ], and orthogonal function [ 578 ] methods. The amounts of iron and cobalt in the samples were evaluated with the help of predetermined calibration plots and presented in Table Absorption of mixed-ligand complexes 3.

The synthesis and characterization of mixed ligand complexes of Cobalt II with phthalic and heterocyclic amines were synthesized and characterized on the basis of elemental analysis, conductometric, magnetic measurements, UV-vis and IR spectral studies [4]. Future trends in spectrophotometric and spectrofluorimetric analysis are discussed [5].

Determination of iron and cobalt in alloy samples.

For photometric determination of cobalt are quite selective reagents o-nitrozofenole group or a similar structure with the oxime group [3]. When cobaltion interact with two molecules of DP, they form doubly-charged anionic complexes, which are extracted with two molecules of protonated Am.

It is also of biological significance thanks to its ability to be an active center of coenzymes, e. Comparision of the results with already reported methods.

However, the studies aiming to find and investigate new photometric reagents with different functional groups are still going on. M solution of the reagent was prepared by dissolving 0. The results obtained in the simultaneous determination of Fe II and Co II are well comparable with the reported methods.

Fine in 2 M sulphuric acid and cobaltous nitrate Qualigens in mL distilled water. The results are presented in Table The soil solutions were further analyzed by a reference method [ 23 ], and biological samples were analyzed by flame atomic absorption spectrophotometer, and the results obtained were compared with those of present method, which indicate the acceptability of the present method.

Abstract Optimized and validated spectrophotometric methods have been proposed for the determination of iron and cobalt individually and simultaneously. Preparation of alloy steel sample solutions [ 30 ] A 0. The product was filtered and dried. View at Google Scholar S.

Formation in the aqueous phase: But excessive intake of iron causes siderosis and damage to organs [ 7 ]. It is a nonmathematical method for the detection and elimination of unwanted absorption during photometric analysis. The number of protons replaced by cobalt in one DP molecule appeared to be one [23, 24].

The absorbance was found to be maximum in the pH range 4. Determination of Cobalt The derivative amplitudes measured for different concentrations of Co II at appropriate wavelengths for 2nd and 3rd order derivative spectra were plotted against the amount of Co II which gave linear plots in the specified concentration regions.

The working solutions were prepared daily by diluting the stock solution to an appropriate volume. Other metal ion solutions were prepared from their nitrates or chlorides in distilled water. A marginal increase in the absorbance was observed in presence of 0.

Other analytical results are presented in Table 5. Vehicle exhaust particles 1 g were dissolved in a mixture of 18 mL of conc.

We are now proposing simple, sensitive and selective direct and derivative spectrophotometric methods for the determination of iron II and cobalt II in various complex materials using 2-hydroxynaphthaldehyde-p-hydroxybenzoichydrazone as chromogenic agent.

Derivative spectrophotometry is a useful means of resolving two overlapping spectra and eliminating matrix interferences in the assay of two-component mixtures using the zero-crossing technique [ 9 — 11 ].

H2SO4, and diluted with water to 1 liter [19]. The pH of these solutions was checked with a pH meter.IX-1 Experiment 9 Spectrophotometric Determination of MW of Cobalt Complex Adapted from Manual for Laboratory Investigations in General Chemistry, Shakhashiri, B.Z.

and Dirreen, G. E., Discussion Many metal coordination complexes absorb energy in the visible part of the electromagnetic. A simple and new simultaneous fourth derivative spectrophotometric method is proposed for the analysis of a two-component system containing cobalt(II) and nickel(II) without separation using 2-hydroxymethoxy benzaldehyde thiosemicarbazone (HMBATSC) as a chromophoric reagent.

Spectrophotometric Analysis of a Two Component Mixture - Free download as Word Doc .doc), PDF File .pdf), Text File .txt) or read online for free. Scribd is the 5/5(7).

Abstract: This paper presents a summary of the theory and procedure applicable to two-component spectrophotometric analysis and describes a system (cobalt(II) and chromium(III) nitrate) that has been found very convenient for student instruction. Mar 04,  · Visible Spectrophotometric Analysis of Cobalt and Nickel Essay Experiment One Visible Spectrophotometric Analysis of Cobalt and Nickel Purpose Understand the function of the Spectronic 20 Spectrophotometer, the Perkin-Elmer recording UV-visible spectrophotometer and reveal the concentrations of nickel and cobalt in an unknown solution.

International Journal of Analytical Chemistry

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Visible spectrophotometric analysis of cobalt and
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